Thermodynamic free energy

Can a reaction spontaneously happen without any energy input?

Thermodynamic free energy

Can a reaction spontaneously happen without any energy input?

Imagine you're trying to push a heavy box up a hill without any help; it's tough and tiring.

A spontaneous reaction is like pushing that box up the hill—it's easier if the hill is downhill (negative change in Gibbs free energy) or if you have a helper (positive entropy change) that makes the push easier.

Example

If the box is downhill, it moves by itself (negative Gibbs free energy), like a spontaneous reaction. If you have a helper (like an increase in entropy), it makes the uphill push (positive Gibbs free energy) easier.

Remember this

A spontaneous reaction happens when the Gibbs free energy change (ΔG) is negative, indicating that the reaction can occur without extra energy.

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